ポリマーサイエンス研究のためのAFM

一般的な用途

• ポリマーブレンドや高分子複合材料のナノメカニカル（弾性率・粘弾性）特性
• 市販包装材の品質試験
• 層の厚さや均一性の測定
• 材料の歪み試験
• 有機エレクトロニクス ー 有機太陽電池の光導電性
• 単鎖ポリマーの引伸ばし
• 熱相転移 ー 融解と結晶化

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"Persistence length of poly(vinyl amine): Quantitative image analysis versus single molecule force response," S. Kozhuharov, M. Radiom, P. Maroni, and M. Borkovec, Macromolecules 51, 3632 (2018). https://doi.org/10.1021/acs.macromol.8b00834

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"Real-time atomic force microscopy imaging of block copolymer directed self assembly," J. Raybin, J. Ren, X. Chen, R. Gronheid, P. F. Nealey, and S. J. Sibener, Nano Lett. 17, 7717 (2017). https://doi.org/10.1021/acs.nanolett.7b03881

"Stem‐cell clinging by a thread: AFM measure of polymer‐brush lateral deformation," M. K. Gunnewiek, S. N. Ramakrishna, A. Di Luca, G. J. Vancso, L. Moroni, and E. M. Benetti, Adv. Mater. Interfaces 3, 1500456 (2016). https://doi.org/10.1002/admi.201500456

"Elastic and viscoelastic characterization of inhomogeneous polymers by bimodal atomic force microscopy," H. K. Nguyen, M. Ito, and K. Nakajima, Jpn. J. Appl. Phys. 55, 08NB06 (2016). https://doi.org/10.7567/jjap.55.08nb06

"Bimodal poly(ethylene-cb-propylene) comb block copolymers from serial reactors: Synthesis and applications as processability additives and blend compatibilizers," A. H. Tsou, C. R. López-Barrón, P. Jiang, D. J. Crowther, and Y. Zeng, Polymer 104, 72e82 (2016). http://dx.doi.org/10.1016/j.polymer.2016.09.088

"Nano-rheology of hydrogels using direct drive force modulation atomic force microscopy," P. C. Nalam, N. N. Gosvami, M. A. Caporizzo, R. J. Composto, and R. W. Carpick, Soft Matter 11, 8165 (2015). https://doi.org/10.1039/c5sm01143d

"Thermoplastic elastomers of alloocimene and isobutylene triblock copolymers," J. Roh, D. Roy, W. Lee, A. Gergely, J. Puskas, and C. Roland, Polymer 56, 280 (2015). https://doi.org/10.1016/j.polymer.2014.11.015

"Fast nanomechanical spectroscopy of soft matter," E. T. Herruzo, A. P. Perrino, and R. Garcia, Nat. Commun. 5, 3126 (2014). https://doi.org/10.1038/ncomms4126

"Measuring the loss tangent of polymer materials with atomic force microscopy based methods," D. G. Yablon, J. Grabowski, and I. Chakraborty, Meas. Sci. Technol. 25, 055402 (2014). https://doi.org/10.1088/0957-0233/25/5/055402

"Resolving sub-molecular binding and electrical switching mechanisms of single proteins at electroactive conducting polymers," A. Gelmi, M. J. Higgins, and G. G. Wallace, Small 9, 393 (2013). https://doi.org/10.1002/smll.201201686

“Improved electrical and flow properties of conductive polyolefin blends: Modification of poly(ethylene vinyl acetate) copolymer/carbon black with ethylene–propylene copolymer,” T. Gkourmpis, C. Svanberg, S. K. Kaliappan, W. Schaffer, M. Obadal, G. Kandioller, and D. Tranchida, Eur. Polym. J. 49, 1975 (2013). https://doi.org/10.1016/j.eurpolymj.2013.03.003

"Nano-scale temperature dependent visco-elastic properties of polyethylene terephthalate (PET) using atomic force microscope (AFM)," C. A. Grant, A. Alfouzan, T. Gough, P. C. Twigg, and P. D. Coates, Micron 44, 174 (2013). https://doi.org/10.1016/j.micron.2012.06.004

"Measuring the interaction between ions, biopolymers and interfaces — one polymer at a time," S. Kienle, T. Pirzer, S. Krysiak, M. Geisler, and T. Hugel, Faraday Discuss. 160, 329 (2013). https://doi.org/10.1039/c2fd20069d

"Poly (acrylamide) films at the solvent-induced glass transition: Adhesion, tribology, and the influence of crosslinking," A. Li, S. N. Ramakrishna, E. S. Kooij, R. M. Espinosa-Marzal, and N. D. Spencer, Soft Matter 8, 9092 (2012). https://doi.org/10.1039/c2sm26222c

"Signature of hydrophobic hydration in a single polymer," I. T. S. Li and G. C. Walker, Proc. Natl. Acad. Sci. U.S.A./em> 108, 16527 (2011). https://doi.org/10.1073/pnas.1105450108

“High-resolution studies of domain switching behavior in nanostructured ferroelectric polymers,” P. Sharma, T. J. Reece, S. Ducharme, and A. Gruverman, Nano Lett. 11, 1970 (2011). https://doi.org/10.1021/nl200221z

"Improved performance of polymer bulk heterojunction solar cells through the reduction of phase separation via solvent additives," C. V. Hoven, X.-D. Dang, R. C. Coffin, J. Peet, T.-Q. Nguyen, and G. C. Bazan, Adv. Mater. 22, E63 (2010). https://doi.org/10.1002/adma.200903677

"Self-assembling polystyrene-block-poly(ethylene oxide) copolymer surface coatings: Resistance to protein and cell adhesion," P. A. George, B. C. Donose, and J. J. Cooper-White, Biomaterials 30, 2449 (2009). https://doi.org/10.1016/j.biomaterials.2009.01.012

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"Nanoindentation of shape memory polymer networks," E. Wornyo, K. Gall, F. Yang, and W. P. King, Polymer 48, 3213 (2007). https://doi.org/10.1016/j.polymer.2007.03.029

"Time-resolved electrostatic force microscopy of polymer solar cells," D. C. Coffey and D. S. Ginger, Nat. Mater. 5, 735 (2006). https://doi.org/10.1038/nmat1712

"Functional polymers: scanning force microscopy insights," P. Samorì, M. Surin, V. Palermo, R. Lazzaroni, and P. Leclère, Phys. Chem. Chem. Phys. 8, 3927 (2006). https://doi.org/10.1039/b607502a

"Using AFM force–distance curves to study the glass-to-rubber transition of amorphous polymers and their elastic–plastic properties as a function of temperature," B. Cappella, S. K. Kaliappan, and H. Sturm, Macromolecules 38, 1874 (2005). https://doi.org/10.1021/ma040135